The Synthesis and Mesophase of Benzoatebased Liquid Crystal Copolymer
In this study, a benzoate-based chiral nematic liquid crystal copolymer using isomannide as chiral crosslinker was produced via radical polymerization. A smectic monomer hydroquinone-bis- 4-4 (allyloxy) beznzoate (M1) was synthesized from ethyl 4-hydroxybenzoate, allyl-bromide and hydroquinone. The chiral LC crosslinkers(M2) was synthesized from the esterification of iso-mannide with 4-hydroxybenzoate. The main-chain liquid crystal copolymer was obtained by UV polymerization using Iregacure 819 as photoinitiator. Chemical structures of the synthesized monomers and polymer were determined by FT-IR and H1NMR and the mesophases were characterized by using differential scanning Calorimetry, polarizing optical microscopy.
Chunxiu Zhang Jialing Pu Yanan Li Sun Sha
Information Recording Materials Lab, Beijing Key Laboratory of Printing & Packaging Materials and Te Information Recording Materials Lab, Beijing Key Laboratory of Printing & Packaging Materials and T
国际会议
The 31st International Congress on Imaging Science(第31届国际影像科学大会 ICIS2010)
北京
英文
856-858
2010-05-12（万方平台首次上网日期，不代表论文的发表时间）