SOLID-STATE NMR INVESTIGATION OF SULFONATED POLY (ETHER ETHER SULFONE) FOR DIRECT METHANOL FUEL CELL

摘要：

Sulfonated poly (ether ether sulfone) (SPEES) membrane with different ion exchange capacity (IEC) was prepared by direct sulfonation method. Some SPEES membrane shows higher proton conductivity (0.011S/cm) but lower methanol permeability (8.18*10-7cm2/s) when IEC was equal to 1.63mmol/g. Solid-state NMR technique was applied to investigate and understand the reasons of different properties between sPEES and Nafion 117. 1H NMR data (e.g. 1H NOESY spectra) shown that there was an interaction between methanol and the backbone of SPEES.

作者: GUIMING ZHONG TAO LI ZIGENG LIU HU CHENG YONG YANG

作者单位: State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College State Key Laboratory for Physical Chemistry of Solid Surfaces, and Department of Chemistry, College

会议类型: 国际会议

会议名称: The 12th Asian Conference on Solid State Ionics(第十二届亚洲固态离子学会议暨第十五届中国固态离子学会议)

会议地点: 武汉

会议语种:英文

页码: 150-157

在线出版日期: 2010-05-02（万方平台首次上网日期，不代表论文的发表时间）