Influence of sintering temperature on phase composition of βSiAlON/ZrN/Al2O3 composite materials
According to the relational thermodynamic data,a phase diagram of Al2O3-ZrSiO4-C-N2 system was presented. Then,by using fused corundum,alumina micro powder,zircon and carbon black as raw materials,βSiA10N/ZrN/Al2O3 composite materials were prepared by nitridation reaction sintering process. The influence of sintering temperature on phase composition of the synthesized composite materials was investigated by X-ray powder diffraction,and the formation process of the composite materials was also analyzed in detail. The results indicated that the βSiAlON/ZrN/Al2O3 composite materials could be prepared at 1773 K by nitridation reaction sintering process. The formation process of the composite materials included the decomposition of zircon,the formation of Si2N2O and si3N4,the formation of O-SiAlON and p-SiA10N as well as the nitridation process of ZrO2.
composite materials phase composition nitridation reaction sintering process thermodynamic analysis
MA Beiyue ZHU Qiang SUN Yong YU Jingkun WANG Jingxin
School of Materials & Metallurgy,Northeastern University,Shenyang 110004,China Beijing General Research Institute for Non-Ferrous Metals,Beijing 100088,China
国际会议
The 10th China-Russia System on Advanced Materials and Technologies(第十届中俄新材料新工艺研讨会)
浙江嘉兴
英文
842-845
2009-10-20(万方平台首次上网日期,不代表论文的发表时间)