Application of Se/CO System in Organic Synthesis:A Brief Introduction
Sonoda et. Al.(1980) reported the carbonylation reaction of aliphatic amines with carbon monoxide (CO) catalyzed by elemental selenium (Se) in 1971. The reaction proceeded smoothly under extremely mild conditions and exhibited high efficiency and selectivity.In the past 37 years,researchers have developed various useful reactions based on the Se/CO system,such as carbonylation of alcohols,reduction or reductive carbonylation of nitroarenes,reduction of ketones,redox carbonylation of nitroarenes and coreagents,cyclocarbonylation reactions,and selenation reactions,etc. These reactions are very important both in synthetic chemistry and life sciences because;1) they provide new synthetic methodologies based on a very cheap catalyst;2) many products of these reactions are known to be useful chemicals;and 3) carbonylation of the nitrogen-containing molecule give peptide bonds,which are closely linked to life sciences.
S.W.Lu Y.Yang J.T.Mei J.Z.Chen X.P.Zhang X.F.Wang X.Z.Liu P,Li X.H.Yuan
National Engineering Research Center for Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,457 Zhongshan Road,Dalian,Liaoning 116011,China
国际会议
The First International Conference on Selenium in the Environment and Human Health(第一届硒与环境和人体健康国际会议)
苏州
英文
101-102
2009-10-01（万方平台首次上网日期，不代表论文的发表时间）