Selenation Reactions with H2Se Generated by Se/CO/H2O System
It was presented in recent years that elemental selenium (Se) was an excellent catalyst to many carbonylation and reduction reactions with carbon monoxide (CO).In these reactions,CO was supposed to be activated by Se through the formation of SeCO.It was also pointed out that SeCO was easily hydrolyzed to form H_2Se and CO_2 in presence of water and a base. On the one hand,SeCO and H_2Se were regarded as activated CO and H_2 in carbonylation and reduction reactions,respectively;on the other hand,both SeCO and H_2Se could be regarded as in situ generated and activated Se species. They could be incorporated into organic molecule and produce organoselenium compounds.Herein,we would like to present our research results on selenation reactions with in situ generated H-2Se by Se/CO/H_2O system.
F.S.Tian Y.H.Chen S.W.Lu
National Engineering Research Center for Catalysis,Dalian Institute of Chemical Physics,Chinese Acad Department of Chemistry,Zhoukou Normal University,Zhoukou,Henan 466000,China
国际会议
The First International Conference on Selenium in the Environment and Human Health(第一届硒与环境和人体健康国际会议)
苏州
英文
103-104
2009-10-01（万方平台首次上网日期，不代表论文的发表时间）