Selenium-Catalyzed Reduction of Aromatic Nitro Compounds with CO/H2O under Atmospheric Pressure

摘要：

Aromatic amines are of significant industrial importance,because they are widely used as the intermediates for synthesis of dyes,pharmaceuticals and agrochemicals. The reduction of aromatic nitro compounds is one of the most common methods to prepare the corresponding aromatic amines. Two methods for reducing the aromatic nitro compounds used in industry are: catalytic hydrogenation and stoichiometric reduction reaction. The catalytic hydrogenation is a clean and convenient method with high yield.However,the selective reduction of aromatic nitro compounds with sensitive functional groups,e.g.,carbonyl,cyano,chloro,and alkenic groups,is often difficult for catalytic hydrogenation,especially the selective reduction of aromatic dinitro compounds.In this case,hydrogen sulfide or variations of this reagents (Zinn reduction) or iron are commonly used,but large amounts of waste are produced.

作者: Xiaozhi Liu Shiwei Lu

作者单位: Chemical Institute of Rare and Scattered Metals,Liaoning University,Shenyang 110036,China National Engineering Research Center for Catalysis,Dalian Institute of Chemical Physics,Chinese Acad

会议类型: 国际会议

会议名称: The First International Conference on Selenium in the Environment and Human Health(第一届硒与环境和人体健康国际会议)

会议地点: 苏州

会议语种:英文

页码: 115-116

在线出版日期: 2009-10-01（万方平台首次上网日期，不代表论文的发表时间）