Synthesis Methods of Nickel Hydrazine Azide (NHA) and Its Characterization

摘要：

Nickel hydrazine azide (NHA) was synthesized using several nickel contained salts under a reasonable control of pH during reacting process. The experiment shown that Ni(Ac)2·4H2O will give an ideal result as the salt for synthesis of NHA. The HAc solution was used to maintain the stable pH of the reacting system. As a powerful primary explosive, NHA could seek its application in civil and military area. Based on the X-ray diffraction (XRD) tests the unit cell parameters were obtained. With the X-ray photoelectron spectra (XPS), the coordinating condition between N and Ni could be inferred clearly. At last, the decomposition process would be recognized by thermal analyses. The Ea and A were calculated using the methods of Ozawa and Kissinger.

关键词： coordination compound synthesis characterization nickel hydrazine azide energetic materials

作者: ZHU Shunguan MA Peng CAO Shijin LI Yan ZHANG Lin

作者单位: School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, Jiangsu, China

会议类型: 国际会议

会议名称: 2009 International Autumn Seminar on Propellants,Ezplosives and Pyrotechnics(2009国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 昆明

会议语种:英文

页码: 1-4

在线出版日期: 2009-09-22（万方平台首次上网日期，不代表论文的发表时间）