Non-Isothermal Method to Estimate Thermal Decomposition Kinetics of Ezplosives Using Mass Spectrometry Ion

摘要：

The non-isothermal method to estimate kinetic parameters from a single curve of MS ion current vs. temperature or time in TG-MS coupling was proposed. The kinetic parameters and mechanism functions obtained by using this method from three types of nitro compounds and two types of azido compounds, including PDADN, GAP, PYX, HNS and HNIW, are in agreement with those obtained by thermal analysis kinetic methods. It is considered that the results of MS ion kinetics will advantage investigation of the initial decomposition mechanism.

关键词： non-isothermal kinetics MS ion ezplosive

作者: FAN Xiping PENG Cuizhi ZHENG Bin LIU Ziru

作者单位: North Institute for Scientific & Technology Information, Beijing 100081, China Xian Modern Chemistry Research Institute, Xian 710065, Shaanxi, China

会议类型: 国际会议

会议名称: 2009 International Autumn Seminar on Propellants,Ezplosives and Pyrotechnics(2009国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 昆明

会议语种:英文

页码: 1-5

在线出版日期: 2009-09-22（万方平台首次上网日期，不代表论文的发表时间）