Study on Thermal Behavior of 3, 6-Bis(1H-1, 2, 3, 4-Tetrazol-5-yl-Amino) -1, 2, 4, 5-Tetrazine(BTATz) by Using Microcalorimeter

摘要：

The thermal decomposition behavior of 3,6-bis(1H-1,2,3,4-tetrazol-5-yl-amino) -1,2,4,5-tetrazine (BTATz) was studied by a Calvet microcalorimeter at four different heating rates. The enthalpies of thermal decomposition at four different heating rates were measured exactly. The kinetic parameters were obtained by Kissinger method and Ozawa method. And the thermodynamic parameters were calculated based on the data obtained by Kissinger method. The critical temperature of thermal explosion (Tb) and the self acceleration decomposition temperature (TSADT) were 262.49 ℃ and 255.23 ℃, respectively.

关键词： 3,6-bis(1H-1,2,3,4-tetrazol-5-yl-amino)-1,2,4,5-tetrazine microcalorimeter critical temperature of thermal ezplosion the self acceleration

作者: XING Xiaoling ZHAO Fengqi XUE Liang YI Jianhua PEI Qing HAO Haixua XU Siyu GAO Hongxu HU Rongzu

作者单位: Xian Modern Chemistry Research Institute, Xian 710065, Shaanxi, China

会议类型: 国际会议

会议名称: 2009 International Autumn Seminar on Propellants,Ezplosives and Pyrotechnics(2009国际推进剂、炸药、烟火技术秋季研讨会)

会议地点: 昆明

会议语种:英文

页码: 1-3

在线出版日期: 2009-09-22（万方平台首次上网日期，不代表论文的发表时间）