WEAK HYDROGEN BONDINGS IN BIODEGRADABLE POLYMERS STUDIED BY INFRARED SPECTROSCOPY AND X-RAY DIFFRACTION

摘要：

We have investigated crystal structure and CH... O=C hydrogen bonding (weak hydrogen bonding) by using infrared (IR) spectroscopy and wide angle X-ray diffraction (WAXD) for poly(3-hydroxybutyrate) (PHB), poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) P(HBco-HHx) (HHx=2.5, 3.4, 10.5, and 12 mol %), and poly (3-hydroxyvalerate) (PHV) (Fig.l). PHB has a CH3 group while PHV has a C2H5 group as a side chain. On the other hand, the HHx has a C3H7 group and P(HB-coHHx) could not make a crystalline form.

作者: Harumi SATO Isao Noda Yukihiro OZAKI

作者单位: School of Science and Technology,and Research Center for Environment Friendly Polymers,Kwansei-Gakui The Procter & Gamble company,USA

会议类型: 国际会议

会议名称: International Symposium on Polymer Physics(2008年国际高分子物理学术会议PP2008)

会议地点: 厦门

会议语种:英文

页码: 226-227

在线出版日期: 2008-06-08（万方平台首次上网日期，不代表论文的发表时间）