Determination of Total Alkalinity and Calcium Concentration of Seawater Rapidly and Automaticly with Small-amount Samples
The means of determing total alkalinity(At) and calcium concentration of small-amount seawater samples using one set of equipments is described. Using automatic potentiometric titrator (MetrohmR 798MPT Titrino), through termostating, increasing the titration reagent volume accuracy, accurate positioning equivalence point and regulating reagent volume every step added, At and calcium can be measured seperately with high precision and limited time. The relative standard deviation of At is lower than 0.10%(±2μmol kg-1)with a single sample consumption of 25cm3 and 9 min while the relative standard deviation of calcium is better than 0.25%( ±26μmol kg-1), sometimes lower than 0.10%(±10μmol kg-1),with a single sample consumption of 1.0 cm3 and 5 min.
automatic potentiometric titrator total alkalinity
Tao Xiaowan Ni Yunyan Pu Xiaoqiang Yang Chun Hu Anping Pu Xiaoqiang
Research Institute of Petroleum Exploration & Development PetroChina Beijing,China Engineering College Guangdong Ocean University Zhanjiang,China Department of Earth Sciences Zhejiang University Hangzhou,China CAS Key Laboratory of Marginal Sea Geology Guangzhou Institute of Geochemistry Guangzhou,China
国际会议
北京
英文
1-4
2009-06-11(万方平台首次上网日期,不代表论文的发表时间)