Optimization and Application of dispersive liquidliquid microeztraction for decaBDE in water samples
A dispersive liquid-liquid microextraction (DLLME) method for the extraction of decabrominated diphenyl ether (decaBDE) at trace level in water samples has been developed. The effect of various experimental factors on the extraction procedure was investigated using multi-factorial design approach. According to the respond surface of extractive recovery (ER), the further optimization of DLLME was carried out and the results were obtained as follow: 1 mL acetone as dispersive system, 10 μL tetrachloroethylene as extractive system, 2.5％ NaCl for the adjustment of ion strength with extraction period of 10 min and pH of 5-9. The optimization conditions were applied to the real water samples for the extraction of decaBDE, and the recovery of the target pollutant was reached with satisfactory, ranging from 94.11％ to 112.35％ for different water matrixes.
dispersive liquid-liquid microeztraction decabrominated diphenyl ether orthogonal design tetrachloroethylene optimization
Yinghong Jian Xianyuan Du Jianlin Liu Yu Li
College of Environment and Resources Jilin University Changchun,China College of Environment and Bio Energy and Environmental Research Center North China Electric Power University Beijing,China Energy and Environmental Research Center North China Electric Power University Beijing,China College
国际会议
北京
英文
1-4
2009-06-11（万方平台首次上网日期，不代表论文的发表时间）