Design of Selective Ozidation Catalysts with Polyozometalates

摘要：

1.Introduction The catalytic function of polyoxometalates (POMs) has attracted much attention because their acidic and redox properties can be controlled at atomic or molecular levels. The strong acidity or oxidizing property of POMs has induced a lot of studies on the heterogeneous and homogeneous catalysis. Additional attractive and technologically significant aspects of POMs in catalysis are their inherent stability towards oxygen donors such as molecular oxygen and hydrogen peroxide. Therefore, POMs could be useful catalysts for liquid-phase oxidation of various organic substrates with hydrogen peroxide or molecular oxygen. Here the following POMs (1)-(3) are introduced (Figure 1).

关键词： design polyozometalates selective ozidation catalysts

作者: Noritaka Mizuno

作者单位: Department of Applied Chemistry,School of Engineering,The University of Tokyo,Tokyo 113-8656,Japan

会议类型: 国际会议

会议名称: 18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

会议地点: 江苏镇江

会议语种:英文

页码: 1-2

在线出版日期: 2008-10-15（万方平台首次上网日期，不代表论文的发表时间）