Rh(I)OR as Finely Tunable Base Catalyst

摘要：

1.Introduction The Bronsted and Lewis bases are one of the benchmark reagents in organic synthesis.We here focused on a finely tunable base catalyst based on transition metal center with various types of ligands.This presentation opens a basic nature of Rh(I)OR complex with suitable ligand.The representative outcome of Rh(I)OMecatalyzed hydration of organonitrile at ambient conditions,Rh(I)OR-catalyzed Aldol-type addition reaction, and Rh(I)OAc-catalyzed rapid hydroboration of vinylarenes are discussed.

关键词： Rhodium Hydration Aldol-type addition Reaction Hydroboration

作者: Kohei Endo Munenao Hirokami Takanori Shibata

作者单位: Department of Chemistry and Biochemistry,School of Advanced Science,Waseda University

会议类型: 国际会议

会议名称: 18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

会议地点: 江苏镇江

会议语种:英文

页码: 33-34

在线出版日期: 2008-10-15（万方平台首次上网日期，不代表论文的发表时间）