会议专题

Anion-triggered Deprotonation of Aromatic Acid for Anion Selective Recognition

1.Introduction Anions are ubiquitous in the wide fields ranging from chemistry,pharmacy,biology, and environmental science.Much effort has been done in design and syntheses of artificial anion receptors,1a-b especially for visible anion recognition.1c-c Recently,we have proposed quite a simple methodology for anion recognition using a commercially available and simple aromatic acid,4-(N,N-dimethylamino)benzoic acid (1), as a probe to prove the strategy.2 In this paper,we wish to report on anion recognition properties of 2-naphthoic acid (2) and 1-pyrenecarboxylic acid (3) being higher homologues of acid 1, and their visible spectral changes by representative anions.3

deprotonation anion visible recognition

Kazuya Kobiro Taishi Wada

Environmental Systems Engineering Course,Graduate School of Engineering,Kochi University of Technology,185 Miyanokuchi,Tosavamada,Kami,Kochi 782-8502,Japan

国际会议

18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

江苏镇江

英文

44-45

2008-10-15(万方平台首次上网日期,不代表论文的发表时间)