New Activation Methods for Imino Compounds and Their Intriguing Reactions

摘要：

1.Introduction Widespread existence of nitrogen-containing compounds such as amino acids, alkaloids, and functional materials coupled with their use as useful synthons prompted us to explore new activation methods for imino compounds and subsequent intriguing reactions.For the synthesis of nitrogen-containing compounds, addition reactions to, -unsaturated imines constitute one of the most straightforward approaches.However, difficulties are always encountered regarding the regioselectivity.On the other hand,imino compounds do not always have enough electrophilicity as compared with their parent carbonyl counterparts.For the activation of imino carbons,use as iminium salts offers one of the solutions.The following new reactions will be discussed.

关键词： α,β-unsaturated imines iminium salts 2-pyridone conjugate addition

作者: Makoto Shimizu

作者单位: Department of Chemistry for Materials,Graduate School of Engineering,Mie University,Tsu,Mie 514-8507,Japan

会议类型: 国际会议

会议名称: 18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

会议地点: 江苏镇江

会议语种:英文

页码: 66-68

在线出版日期: 2008-10-15（万方平台首次上网日期，不代表论文的发表时间）