Phosphole-Based Materials:Synthesis,Photophysical Properties and Application

摘要：

1.Introduction π-Conjugated systems containing a main group element have attracted considerable interest.Phosphole is an interesting building block for the construction of conjugated systems,where an interaction between the butadiene π* orbital and the low-lying σ*(P-R) orbital takes place in the ring.In addition, the central phosphorus atom allows tuning the electronic properties of the materials by e.g.oxidation and coordination to a metal.This paper reports synthesis and properties of phosphole-based materials.

关键词： phosphole dendrimer π-conjugate system

作者: Masato Tanaka

作者单位: Chemical Resources Laboratory,Tokyo Institute of Technology,4259-R1-13 Nagatsuta,Midori-ku,Yokohama 226-8503,Japan

会议类型: 国际会议

会议名称: 18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

会议地点: 江苏镇江

会议语种:英文

页码: 103-105

在线出版日期: 2008-10-15（万方平台首次上网日期，不代表论文的发表时间）