Syntheses and Crystal Structures of Two Octacyanometalate Networks:Ni(L1)3W(CN)82·4H2O and Ni(L2)2Mo(CN)8·8H2O

摘要：

1.Introduction Recently, octacyanometallated-based assemblies have played an important role in the construction of molecule-based functional materials owing to their unique structures and physicochemical properties.1 However, only several NiⅡ/MⅣ/Ⅴ (M=Mo, W, and Nb) networks have been reported so far. To extend the properties-structural correlation of this system, we have obtained two-and three-dimensional bimetallic assemblies NiⅡ(LⅠ)3WⅤ(CN)82·4H2O (L1=3,10-dipropyl-1,3,5,8,10,12 -bexaazacyclotetradecane), 1, and NiⅡ(L2)2MoⅣ(CN)8·8H2O (L2=3,10-diethyl-1,3,5,8,10,12 -hexaazacyclotetradecane), 2. Single crystals of 1 and 2 were obtained successfully by slow diffusion and characterized structurally by single-crystal X-ray diffraction.

关键词： crystal structures nickel compounds octacyanometalate

作者: Ai-hua Yuan Wen-yan Liu Hu Zhou Su-yan Qian

作者单位: School of Material Science and Engineering,Jiangsu University of Science and Technology,Zhenjiang,212003,China

会议类型: 国际会议

会议名称: 18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

会议地点: 江苏镇江

会议语种:英文

页码: 313-314

在线出版日期: 2008-10-15（万方平台首次上网日期，不代表论文的发表时间）