Synthesis,Structure and Porous Properties of Prussian Blue Complez KCdCr(CN)6·H2O

摘要：

1.Introduction The structural topology characteristic of the Prussian Blues is a simple cubic (α-Po type) network, with linear bridging of the octahedral metal ions by cyanide anion which defines pores within the framework. In this simple cubic network, all transitional metals located in the surface of pores may interact with guest molecules in the pores. In comparison with other nanoporous phases such as zeolites, these materials have lower framework densities and higher surface areas and lower enthalpies of adsorption. Therefore, these materials are ideally suited to high gas mass loadings. Although some studied progress in Prussian-blue analogues have been obtained so far, detailed structural studies based on single crystals are limited, and the gas storage properties of the complexes based on Cr(CN)63-havent been reported.

关键词： cyano-bridged polymer synthesis crystal structure absorption and desorption properties

作者: Chaoxia Chu Aihua Yuan Wenyan Liu Xiangqian Shen Xianfeng Meng

作者单位: School of Material Science and Engineering,Jiangsu University of Science and Technology,Zhenjiang 21 School of Material Science and Engineering,Jiangsu University,Zhenjiang 212003,China

会议类型: 国际会议

会议名称: 18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会)

会议地点: 江苏镇江

会议语种:英文

页码: 360-361

在线出版日期: 2008-10-15（万方平台首次上网日期，不代表论文的发表时间）