Tungsten ozide nanostructures growth in HFCVD system by slow positron beam
Tungsten oxide (WOx) nanostructures were prepared by a hot filament chemical vapor deposition (HFCVD) system. Two series of samples were synthesized by adjusting filaments temperature (Tf) and oxygen gas concentration (OGC). The crystallinity and stoichiometry were highly related to Tf and OGC. The evolution of stoichiometry and types of defects was illuminated by slow positron implantation spectroscopy (SPIS). A turning point of Tf=1750℃ was found that at this point the crystallinity and stoichiometry natures were the best. In order to develop the chemical phase from substoichiometric to stoichiometric, the oxygen gas concentration in the mixture gas during deposition should be raised to an appropriate level.
tungsten ozide nanostructure nanobunlde HFCVD slow positron
J.Lou B.J.Ye X.P.Wang H.M.Weng H.J.Du Z.B.Zhang
Department of modern Physics,University of Science and Technology of China,Hefei 230026,P.R.China Department of Physics,University of Puerto Rico,P.O.Box 23343,San Juan,PR 00931,USA
国际会议
第九届国际正电子与正电子素国际会议(9th International Workshop on Positron and Positronium Chemistry)(PPC–9)
武汉
英文
195-197
2008-05-11(万方平台首次上网日期,不代表论文的发表时间)