DETERMINATION OF THE ACTIVATION ENERGY OF THE DECOMPOSITION OF FLAME RETARDED HIPS UNDER SPECIAL CONSIDERATION OF THE COMPENSATION EFFECT

摘要：

The kinetic triplet of high impact polystyrene (HIPS) and fire retarded HIPS was determined using a new method which eliminates the compensation effect after the calculation of the activation energy and the pre-exponential factor using the Kissinger and the Ozawa method. It was found that the change in the pre-exponential factor has a strong impact on the degradation. The degradation follows nucleation kinetics described by Avrami-Erofeev kinetics and power-laws.

作者: Guido Grause Jun Ishibashi Tomohito Kameda Thallada Bhaskar Toshiaki Yoshioka

作者单位: Graduate School of Environmental Studies, Tohoku University, Aramaki Aza Aoba 6-6-11,Aoba-ku Sendai Process, Reaction Engineering, Corrosion, Biomass Conversion Area,, Indian Institute of Petroleum (I

会议类型: 国际会议

会议名称: The 5th International Symposium on Feedstock and Mechanical Recycling of Polymeric Materials(ISFR2009)(第五届高分子材料回收国际研讨会)

会议地点: 成都

会议语种:英文

页码: 5-9

在线出版日期: 2009-10-11（万方平台首次上网日期，不代表论文的发表时间）