STUDY ON METHANOLYSIS OF WASTE POLYETHYLENE TEREPHTHALATE) IN IONIC LIQUID

摘要：

The methanolysis of poly(ethylene terephthalate) (PET) was studied using ionic liquid 1- n-butyl-3-methylimidazolium chloride as solvent and zinc acetate as catalyst. The effects of reaction temperature, time, dosages of solvent and catalyst on methanolysis results were examined. The obtained optimum reaction conditions were reaction temperature 160℃, reaction time 3h, m(solvent):m(PET)=2:l, m(zinc acetate):m(reaction mixture)=l:20. Under above conditions, the conversion of PET could reach 100％. After easily separated from the product, the system of solvent and catalyst could be reused 8 times without obvious decrease in conversion of PET. Therefore, an environmental friendly approach for methanolysis of waste PET was developed.

作者: Fusheng Liu Xiao Cui ShitaoYu Zhuo Li Xiaoping Ge

作者单位: College of Chemical Engineering, Qingdao University of Science and Technology,Qingdao 266042,China

会议类型: 国际会议

会议名称: The 5th International Symposium on Feedstock and Mechanical Recycling of Polymeric Materials(ISFR2009)(第五届高分子材料回收国际研讨会)

会议地点: 成都

会议语种:英文

页码: 272-276

在线出版日期: 2009-10-11（万方平台首次上网日期，不代表论文的发表时间）