THE NON-EQUILIBRIUM SALT FORMING PHASE DIAGRAM: APPLICATION TO EFFECTIVELY UTILIZE BRITTEN RESOURCE

The non-equilibrium state salt forming phase diagram, include primary region and extended Region, are different from solubility phase diagram and metastable phase diagram, which can be used to express the salt forming regions in the non-equilibrium state of evaporation and crystallization process in the high temperature for the multi-component salt-water systems. In this paper the residual brine resource of Tulantai salt-lake(China), Dongtai Salt-lake(China), Jilantai Salt-lake(China), Qarun Salt Lake(Egypt) and Seawater which after precipitation of pure sodium chloride, was analyzed. The benefit strategy needed by bittern utilization was given by compare Na2SO4 based plan with MgSO4 based Plan. The operations required by evaporation processes at 25℃, 75℃, 100℃ and 150℃ were simulated by a path through the solubility diagram and salt-forming diagram of Mg2+-Na+//SO42--Cl--H2O system. The yield and recovery rate of salt and sulfate were calculated. The results show, (1) more benefit of MgSO4 based plan than that of Na2SO4 based plan. (2) MgSO4 based plan can be putted in practice, but in the middle temperature and vacuum evaporation process. (3) the yield of NaCl for the several bittern in the MgSO4 based plan were 1.53,2.01,2.95,19.48 and 6.8 times respectively than that of Na2SO4 based plan in the normal temperature, the recovery rate of sulfate were increased by 18.46%, 27.51%, 38.23%, 55.13% and 79.99% respectively.
Phase Diagram Non-Equihbrium State Britten Salt Lake Seawater Salt
Zhou Huan Pan Lei Chen Yadong Yuan Jianjun Sha zuoliang
College of Marine Science and Engineering, Tianjin University of Science and Technology Tianjin 3004 College of Science, Northwest Agriculture & Forestry University Shan xi 712100
国际会议
9th International Symposium on Salt(第九届世界盐业大会)
北京
英文
1190-1196
2009-09-05(万方平台首次上网日期,不代表论文的发表时间)