Investigations Of Electron Attachment To Nitro-Compounds Towards Ezplosives
Electron attachment to gas phase nitrobenzene, all three isomers of mononitrotoluene and 2,4,6-trinitrotoluene is studied by means of two crossed electron-molecular beam experiments. We point out the formation of long-lived metastable parent anions and the most abundant anions produced via dissociative electron attachment (DEA). The experimental results are supported by quantum-chemical calculations, to determine the electronic configuration of selected molecular orbitals or the electrostatic potential mapped on an isosurface of the total electron density to find preferential sites of electron attachment.
Electron Attachment Nitrobenzene Mononitrotoluene Trinitrotoluene Ezplosives
A.Mauracher S.Denifl M.Probst T.D.Mark P.Scheier
Institut fur Ionenphysik und Angewandte Physik, Leopold-Franzens-Universitdt Innsbruck Technikerstr.25, A-6020 Innsbruck, Austria
国际会议
北京
英文
157-165
2008-10-27（万方平台首次上网日期，不代表论文的发表时间）