NUMERICAL SIMULATION ON HYDROCARBON TRANSFORMING MECHANISM DURING COAL REBURNING

摘要：

On the basis of GRI3.0 database, numerical simulation of hydrocarbon transforming mechanism using sensitive analysis method of CHEMKIN was discussed. The results show that H, O and OH are activated groups which are necessary to startup a series of important radicel reactions. Light hydrocarbon does not have reducing functions on NO with itself. Generally, they are transformed into CHi, which could react with NO to reduce NO emission effectively. CH3 is the main reductive component while CHi reacts with NO and reduces it directly. The main final reacting product is HCN which has promoter action for NO reduction. On the contrary, when O, O2 and other oxidizers exist, these hydrocarbon groups may be directly oxidized into CO, CO2, and so on. In a certain extent, these might cut down NO reduction efficiency.

关键词： Sensitivity analysis Radicel reaction Hydrocarbon Transforming mechanism

作者: Junjie FAN Zhongxiao ZHANG Jing JIN

作者单位: Institute of Combustion and Gasification Engineering, College of Power Engineering, University of Shanghai for Science & Technology, Shanghai, China, 200093

会议类型: 国际会议

会议名称: 第六届煤燃烧国际会议(The 6th International Symposium on Coal Combustion)

会议地点: 武汉

会议语种:英文

页码: 680-685

在线出版日期: 2007-12-01（万方平台首次上网日期，不代表论文的发表时间）