A review on the solid-state ionics of electrochemical intercalation processes: How to interpret properly their electrochemical response
In this paper, we discuss the electrochemical response of three types of insertion electrodes: graphite and transition metal oxides that intercalate reversibly with lithium, electronically-conducting polymers with red-ox activity that can be doped reversibly, both positively and negatively (i.e., at high and low potentials), and Chevrel phases with Mo-S-Se elements, which intercalate reversibly with both lithium and magnesium. The main point of interest is the correlation among electrochemical kinetics, impedance, surface chemistry, 3D structure, and morphology of these systems, studied by the use of electroanalytical tools in conjunction with XRD, microscopy and spectroscopy. Magnesium insertion into Chevrel phases and Li insertion into most of the electrodes relevant to Li batteries involves phase transition. Thereby, the electrodes kinetics are affected by interfacial charge transfer processes, solid-state diffusion, and the moving of boundaries between phases. The electrochemical response of the electrodes reflects all these processes. However, the identification of the relevant time constants that affect the measured electrochemical behavior is not trivial. Efforts are made in this paper to provide comprehensive guidelines regarding the proper use of fine electrochemical tools for the study of various types of insertion electrodes.
Conjugated (conducting) polymers Intercalation electrodes Electroanalytical techniques Li batteries Mg batteries SS diffusion
Doron Aurbach Mikhail D.Levi Elena Levi
Department of Chemistry, Bar-Ilan University, Ramat-Gan, 52900, Israel
国际会议
The 16th International Conference on Solid State Ionics(第十六届国际固态离子学会议)
上海
英文
742-751
2007-07-01（万方平台首次上网日期，不代表论文的发表时间）