Polymer electrolyte membranes derived from modified poly (phthalazinone ether ketone) for fuel cell applications

摘要：

The sulfonated poly(phthalazinone ether ketone) (SPPEK) membrane and quaternized poly(phthalazinone ether ketone) (QPPEK) membrane were prepared by the casting method from corresponding materials. Suitable thermal and mechanical properties of modified PPEK membranes were proved by thermogravimetry analysis and tensile machine. The ionic conductivities and methanol permeabilities of the two kinds of membranes were tested and compared with each other. The proton conductivity of SPPEK membrane and the hydroxide ion conductivity of QPPEK. membrane reached respectively the maximum of 0.031 S/cm at 95℃ and of 0.014 S/cm at 80℃ under 100% relative humidity. Both the methanol permeabilities at room temperature were lower than that of Nafion117.

关键词： Poly(phthalazinone ether ketone) Polymer electrolyte membrane Fuel cell

作者: Hongwei Zhang Zhentao Zhou

作者单位: College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510640, PR China

会议类型: 国际会议

会议名称: The 16th International Conference on Solid State Ionics(第十六届国际固态离子学会议)

会议地点: 上海

会议语种:英文

页码: 1296-1299

在线出版日期: 2007-07-01（万方平台首次上网日期，不代表论文的发表时间）