Atomic layer deposition of LSM cathodes for solid ozide fuel cells
For solid oxide fuel cells (SOFCs) to succeed as a next-generation, clean energy conversion device, they must be made to run more efficiently at low temperatures <500℃. To improve electrode kinetics at these lower temperatures, we investigate using atomic layer deposition (ALD) to fabricate mixed electronic-ionic conducting electrodes of (LaxSr1-x)MnO3 (LSM). Lanthanum oxide was grown from La(Me4Cp)3 and water with a source temperature of 220℃ with a stoichiometry of La2O3. Strontium oxide was grown from Sr(n-PrMe4Cp)2 and water with a precursor sublimation temperature of 210℃ and a stoichiometry of SrO, with little carbon contamination. Manganese oxide was grown from Mn(Me4Cp)2 at a source temperature of 180℃ and water as oxidant; the stoichiometry was confirmed to be MnO2. LSM was grown at a growth rate of ～3.5 nm/cycle, where one cycle was composed of the following sequence: La/H2O/La/H2O/Mn/H2O/Sr/H2O/Mn/H2O/La/H2O/La/H2O. LSM was crystalline as deposited when grown on crystalline yttria-stabilized zirconia (YSZ) substrates. On fuel cells with LSM as the 95 nm thick, dense cathode, 100 nm thick, dense YSZ as electrolyte, and porous 80 nm thick Pt anode, a peak power density of 0.2 μW/cm2 was achieved at 450℃. Electrochemical impedance spectroscopy shows that low oxygen diffusivity in LSM and slow kinetics of the oxygen reduction reaction on LSM were the limiting resistances in the fuel cell, suggesting that LSM is not an optimal low temperature cathode.
Atomic layer deposition (ALD) Mized conductors (MEICs) (LazSr1-z)MnO3 (LSM) Solid ozide fuel cells (SOFCs)
Timothy P.Holme Changkeun Lee Fritz B.Prinz
Mechanical Engineering, Stanford University, 440 Escondido Mall, Stanford, CA 94305, United States
国际会议
The 16th International Conference on Solid State Ionics(第十六届国际固态离子学会议)
上海
英文
1540-1544
2007-07-01（万方平台首次上网日期，不代表论文的发表时间）