Anaerobic Fermentation for Hydrogen Production from 11 Organic Acids10
The experiments described in this paper investigate anaerobic fermentation for hydrogen production from eleven organic acids using anaerobic activated sludge as inoculum. It was shown that hydrogen gas was produced when using citric, malic, lactic, formic, pyruvic, oxalic, and fumaric acid, and the hydrogen potential at 25℃ for those acids is 171.3, 117.4, 93.5, 79.6, 75.6, 24.6 and 23.7ml/g, respectively. However, no hydrogen was generated when using succinic, butyric, propionatic and acetic acid. According to the hydrogen potential, energy conversion can be calculated and is lower due to accumulation of butyric, propionatic and acetic acid that cant be metabolized by hydrogen-producing bacteria. It also indicates that whether organic acids investigated can produce hydrogen gas or not through anaerobic fermentation mostly depends on its free energy change (△G°)ofa hydrogen-producing reaction, and ifthe△G° is much more than 0, they cant produce hydrogen.
Hydrogen Production Hydrogen Potential Organic Acid Anaerobic Fermentation
Li Jianchang Liu Li Zhang Wudi
Provincial Key Lab of Rural Energy Engineering,Yunnan Normal University,Kunming 650092,PR. China Chemical Engineering School of Yunnan Province,Kunming 650050,PR. China
国际会议
广州
英文
848-854
2008-12-03(万方平台首次上网日期,不代表论文的发表时间)