Study on the Reaction Rate of Polysilane Formation by Electroreduction

摘要：

Polysilanes were synthesized by electroreduction of different monomers such as CH3HSiCl2,PhSiCl3,CH3SiCl3 and (CH3)2SiCl2 with Mg electrodes under ultrasonic radiation.The effects of monomers and additives on the reaction rate were investigated.Polymerization of PhSiCl3 among the four monomers showed the highest rate.Without additive,the percent of Si-Cl bonds remaining for CH3HSiCl2 were 29.5％ when electricity reached 15.5％ of theoretic value.However, the percent of Si-Cl were 17.5％～29％ when electricity arrived at 10％ of theory value with additives.Different efficiency of the additives(p-dibromobenzene(DBB),naphthalene(NAPH)and anthracene(ANTH))was also observed in the polymerization reaction.P-dibromobenzene was proved the most effective additive.Based oil the observations,possible mechanisms of the polymerization were proposed.

关键词： electrosynthesis reaction rate polysilane monomers additives

作者: ZHANG Fengjun CHEN Mingliang OH Wonchun

作者单位: Department of Advanced Materials & Science Engineering,Hanseo University,Chungnam 356-706,Korea;Anhu Department of Advanced Materials & Science Engineering,Hanseo University,Chungnam 356-706,Korea

会议类型: 国际会议

会议名称: The 2nd International Conference on Asian-European Environmental Technology and Knowledge Transfer(第二届亚欧环境技术及知识转化国际研讨会)

会议地点: 合肥

会议语种:英文

页码: 428-431

在线出版日期: 2008-06-05（万方平台首次上网日期，不代表论文的发表时间）