Low-Temperature Reducing Chemistry:Synthetic Conditions of SrFeO2

摘要：

We recently discovered that a novel low-temperature reaction of SrFeO3 with CaH2 as a powerful reducing agent resulted in the formation of SrFeCh that bears a square-planar coordination around iron. The obtained new oxide is thus of special importance not only due to the novelty of the coordination geometry but also due to intriguing properties such as an extremely high magnetic ordered temperature and oxygen absorptions at moderate temperatures. We show here a thorough inspection of the reaction conditions.

关键词： SrFeO2 infinite layer soft chemistry hydride reduction.

作者: C.Tassel Y.Tsujimoto T.Watanabe H.Kageyama K.Yoshimura

作者单位: Department of Chemistry,Graduate School of Science,Kyoto University,Kyoto 606-8502,Japan

会议类型: 国际会议

会议名称: The 10th International Conference on Ferrites(2008中国国际铁氧体研讨会)

会议地点: 成都

会议语种:英文

页码: 32-34

在线出版日期: 2008-10-10（万方平台首次上网日期，不代表论文的发表时间）