Highly Selective Synthesis of Hexakis(m-phenylene imine) Macrocycles Using the Reversibility in Formation-Cleavage of lmine Linkage

摘要：

An AB-type monomer was self-polycondensated in THF in the presence of water as an initiator to give a novel macrocycle, cyclic hexakis (m-phenylenenitrilomethylidyne) (Cm6). An addition of acetic acid instead of water to this polymerization system enhanced the rate of formation dramatically. The reversibleformation-collapse mechanism and its controllable aggregation behaviors will be also reported.

关键词： macrocycles polyimines polyazomethines selective synthesis formation-collapse mechanism

作者: Kozo ISHIDA Seitaro OISHI Toshihiko MATSUMOTO Mitsuhiro FUKUDA Jiaping LIN

作者单位: Center for Nano Sci.& Technol.,Tokyo Polytechnic Univ.,Atsugi,Japan Hyogo Univ.of Teacher Education,Yashiro-cho,Hyogo,Japan East China Univ.of Sci.& Technol.,Shanghai,China

会议类型: 国际会议

会议名称: 5th East-Asian Polymer Conference(第5届东亚高分子学术研讨会)

会议地点: 上海

会议语种:英文

页码: 216-217

在线出版日期: 2008-06-03（万方平台首次上网日期，不代表论文的发表时间）