Synthesis and Properties of Phenylphosphinic Acid-Containing Amphiphilic Polymers by Reversible Addition-Fragmentation Transfer (RAFT) Polymerization

摘要：

In the past decades, phosphorous-containing polymers received much attention of polymer chemists, since they have adhesive properties to metals1,2, bone and dentin3,4, as well as flame retardation property5. In this communication, a novel phosphorous-containing monomer, 3-2-(acryloyloxy)ethoxy-3-oxopropyl(phenyl) phosphinic acid (AEOPA) (Scheme 1) was first synthesized, and then the polymerizations were carried out at 60°C in the presence of benzyl 1H-imidazole-1-carbodithioate (BICDT), which is a good RAFT agent for methyl acrylate.

作者: Jing Tang Daoben Hua Jianlin Jiang

作者单位: Key Laboratory of Organic Synthesis of Jiangsu Province,School of Chemistry and Chemical Engineering,Suzhou University,Jiangsu Province 215123,P.R.China

会议类型: 国际会议

会议名称: 5th International Symposium on High-Tech Polymer Materials(HTPM-V)(第五届国际高技术高分子材料学术会议)

会议地点: 北京

会议语种:英文

页码: 222-223

在线出版日期: 2008-10-27（万方平台首次上网日期，不代表论文的发表时间）