New sulfonated monomers and polymers based on TNT derivatives
(0) New sulfonated and non-sulfonated monomers-dinitrocompounds and diamines-were prepared on the basis of 1,3,5-trinitrobenzene-TNT demethylation product. Syntheses of the above-mentioned monomers were carried out in accordance with Scheme (1):Sulfonated and non-sulfonated dinitrocompounds obtained were interacted with different binuclear bis-phenols under the conditions of aromatic nitrodisplacement reactions(Scheme 2):Polyethers of moderate molecular weights were prepared on the basis of dinitrocompounds containing electron-withdrowing sulfone bridging groups-3,5-dinitrodiphenyl sulfone-4-sulfonic acid. Copolymers and blends with othersulfonated polymers were prepared to improve the film-forming properties of the polyethers developed.High molecular weight polynaphthylimides were prepared by the interaction of sulfonated diamines containing electron-donating ether and sulfide bridging groups-3,5-diaminodiphenyl ether-4-sulfonic acid and 3,5-diaminodiphenyl sulfide-4-sulfonic acid-with bis(naphthalic anhydrides) (Scheme 3):General properties (including electrochemical characteristics) of the polyethers and polynaphthylimides obtained were investigated.
A.L.Rusanov C.lojoiu I.-Y.Sanchez V.Yu.Voitekunas M.-J.M.Abadie L.G.Komarova E.G.Bulycheva M.G.Bugaenko V.A.Tartakovskiy S.A.Shevelev M.D.Dutov O.V.Serushkina V.A.Mezhnev
A.N.Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences,Vavilov Str.28,Mosco LEPMI ENSEEG,Universite Joseph Fourier,Saint Martin dHeres,France Laboratory of Polymer Science and Advanced Organic Materials-LEMP/MAO,CC 021,Universite Montpellier N.D.Zelinskiy Institute of Organic Chemistry,Russian Academy of Sciences,Leninsky Prosp.42,Moscow,11
国际会议
5th International Symposium on High-Tech Polymer Materials(HTPM-V)(第五届国际高技术高分子材料学术会议)
北京
英文
5-6
2008-10-27（万方平台首次上网日期，不代表论文的发表时间）