The selective reduction of nitroarenes with Fe in pressurized CO2 - H2O medium

摘要：

A new method for reduction of nitroarenes using metallic iron in CO2 -H2O medium has been developed. o-Chloronitrobenzene can be reduced to the corresponding amine with a yield of 99% under the optimized conditions. The method is also applicable for the reduction of other substituted nitroarenes. After the reduction, carbonic acid is self-neutralized on releasing of CO2. The method is environmentally benign, easy scaled-up and applicable for preparation of substituted anilines.

作者: Ge Gao Shijuan Liu Bin Zhao Jingyang Jiang

作者单位: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China

会议类型: 国际会议

会议名称: The 12th Asian Pacific Confederation of Chemical Engineering Congress(第十二届亚太化工联盟大会暨化工展览会)

会议地点: 大连

会议语种:英文

在线出版日期: 2008-08-04（万方平台首次上网日期，不代表论文的发表时间）