Bioheapleaching Pilot Plant Tests on Nickel Sulphide Ore
The Mojiang nickel deposit is situated in Mojiang county, yunnan province, a tropical area in the southwestern China.The known geological resource (measured and inferred) includes 4 million tons of nickel sulphide ore at an average grade of 0.50% Ni and 0.34% As.Nickel minerals are mainly gersdofffite (NiAsS), millerite(NiS), morenosite (NiSO4·7H2O), and more than 50% nickel minerals is gersdorffite which contains arsenic. Pyrite is the dominant sulfide mineral, 22% in the ore and part of nickel minerals are locked in pyrite. It is difficult to attain the nickel concentrate quality allowed by a smelter and the acceptable nickel recovery through flotation due to the high arsenic in the ore and the nickel minerals locked in pyrite.The shake flask tests and column tests for nickel recovery from the Mojiang nickel sulfide ore had been finished by the end of 2003. The column bioleaching tests were carried out using the columns with diameter of 120 mm and height of 1200 mm, and 70% of nickel dissolution was attained in 300 days. A 10,000t pilot test heap was built in the Mojiang Nickel Mine by June 2003.The ore used in the test heap was supplied from the underground mine and was crushed to -20 mm before being feeding to the test heap, which is 4～5 m high, 30 m wide and 50 m long.The naturally adapted mesophile and moderate thermophile have been inoculated into the leaching pile by June 2003. The operating temperature in the heap ranges from 38℃ to 55℃, varying with season. 30% of nickel dissolution was achieved in 3 months and the typical pregnant leach solution (PLS) contains 2～3 g/L Ni and 20～30 g/L Fe. The Ni sulfide which was produced by using Na2S 10 t/t·Ni contains 16%～20% Ni and Ni recovery was 98%. 70% of Ni dissolution is expected in 12 months. The test heap was scaled up to 60,000 t of ore per year by mid of 2005.In this paper metallurgical studies and performance of the pilot test heap will be described. The results of mineralogy, shake flask tests and column tests on bioleaching of the nickel sulfide ore are reviewed. The key test heap operation parameters, the performance of bio-heap leahing-Na2S precipitation, ferrous oxidation-ferric precipitation-Na2CO3 precipitation, bacteria in the pile, water and acid balance, effluent disposal, capital and operation costs are also discussed.
Nickel sulfide Bio-heap leaching Precipitation Pilot plant Acid and iron balance
J. K. Wen R. M. Ruan G. C. Yao X. Liu H. Zang
National Engineering Laboratory of Biohydrometallurgy, General Research for Nonferrous Metals, Beijing, China
国际会议
XXIV International Mineral Processing Congress(第24届国际矿物加工大会)
北京
英文
2611-2615
2008-09-24（万方平台首次上网日期，不代表论文的发表时间）