Improved Debenzylation of Caged Polycyclic Amine Hexabenzylhexaazaisowurtzitane

摘要：

The yield of debenzylation of hexabenzylhexaazaisowurtzitane was not actually more than 80％ with 10-15％ byproducts. However, we have successfully achieved a yield of 92.1％ with the product purity of 95.8％ by optimally control the hydrogenolysis parameters such as temperature, catalyst and solvent. The selected parameters could facilitate the debenzylation and retard the cleavage of caged derivatives as revealed by the attenuated total reflection fourier transform infrared spectroscopy.

关键词： hexaazaisowurtzitane debenzylation HNIW

作者: CHEN Huaxiong CHEN Shusen JIN Shaohua LI Lijie

作者单位: School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China

会议类型: 国际会议

会议名称: 2007国际推进剂、炸药、烟火技术秋季研讨会(The 2007 International Autumn Seminar on Propellants,Explosives and Pyrotechnics)

会议地点: 西安

会议语种:英文

页码: 30-33

在线出版日期: 2007-10-23（万方平台首次上网日期，不代表论文的发表时间）