Preparation of TATB-BTF Nanocomposite Energetic Materials Using Solvent Vaporizing Method
The preparation of nanocomposite energetic materials is currently a very active and exciting research area. In this paper, TATB-BTF composite particles were prepared through solvent vaporizing method, also the composite particles structure, thermal performance and mechanic sensitivity were characterized by scanning electron microscopy(SEM), differential scanning calorimetric(DSC) and impact sensitivity experiment. The SEM images revealed that most TATB-BTF composite particles were around 200nm in diameter, these nanocomposite particles did not show visible shape change and particles size distribution became narrower and smaller compared with the original ultrafine TATB particles whose size was around 400nm. These evidence indicated that ultrafine TATB aggregations were broken up and dispersed during the vaporization of solvent and construction of nanocomposite. The thermal decomposition experiments showed that thermal decomposition peaks of both two components forming TATB-BTF composite appeared on DSC curves. The impact sensitivity of TATB-BTF nanocomposite were significantly reduced compared with that of the physical mixture although their composition and ratio were the same.
energetic materials nanocomposite solvent vaporizing method sensitivity SEM DSC TATB BTF
ZENG Guiyu NIE Hude HUANG Hui LIU Lan ZHAO Lin LU Chunxu
Institute of chemical materials, China Academy of Engineering Physics, Mianyang 621900, Sichuan, Chi Institute of chemical materials, China Academy of Engineering Physics, Mianyang 621900, Sichuan, Chi School of Chemistry Engineering, Nanjing University of Science & Technology, Nanjing 210094, Jiangsu
国际会议
西安
英文
52-54
2007-10-23（万方平台首次上网日期，不代表论文的发表时间）