Synthesis and Thermal Decomposition of N, N-bis (benzofuroxan) Oxalic Amide

摘要：

N, N-bis (benzofuroxan) oxalic amide was synthesized from the starting materials of oxalyl chloride and 3,5-dichloroaniline, and was characterized by elemental analysis, IR, 1H NMR and MS. The thermal decomposition reactions of the title compound at different heating rate are tested by differential scanning calorimeter (DSC). The kinetics parameters of the reactions of the compound are calculated by Kissingers method. The apparent activation energy (Ea) is 226.7kJ-mol1 and the pre-exponential constant (A) is 1023.17 S-1. It is presupposed that N, N-bis (benzofuroxan) oxalic amide will be a promising explosive.

关键词： N, N-bis (benzofuroxan) oxalic amide benzofuroxan synthesis characterization thermal properties

作者: LU Lianying ZHANG Kunling YUE Hongkun LIANG Huixa MU Wei LIU Dexin

作者单位: Chemistry Department, Shijiazhuang University, Shijiazhuang 050035, Hebei, China Chemical Engineering Department, Shijiazhuang Vocational Institute of Technology, Shijiazhuang 05008 Yinguang Chemical Industry Group Co. Ltd, Baiyin 730900, Gansu, China

会议类型: 国际会议

会议名称: 2007国际推进剂、炸药、烟火技术秋季研讨会(The 2007 International Autumn Seminar on Propellants,Explosives and Pyrotechnics)

会议地点: 西安

会议语种:英文

页码: 66-68

在线出版日期: 2007-10-23（万方平台首次上网日期，不代表论文的发表时间）