Preparation, Characterization and Kinetics of Thermal Decomposition of Some Transition Metal Nitrate Complexes of Piperidine

摘要：

Nitrate complexes of 3d-transition metal with piperidine have been prepared and characterized. All these complexes are quiet stable at room temperature. Thermal decomposition of these complexes have been studied by using thermogravimetry (TG) and differential thermal analysis (DTA). Kinetics of their thermal decomposition was evaluated by applying model-fitting as well as isoconversional methods. Kinetics of thermal decomposition these complexes have been evaluated using mechanism based fourteen kinetics models and isoconversional method. Ignition delay studies have also been undertaken.

关键词： transition metal nitrate complexes iso-conversional ignition delay isothermal TG model fitting thermal decomposition

作者: G. SINGH I.P.S. KAPOOR Dinesh KUMAR

作者单位: Department of Chemistry, DDU Gorakhpur University, Gorakhpur-273009, India

会议类型: 国际会议

会议名称: 2007国际推进剂、炸药、烟火技术秋季研讨会(The 2007 International Autumn Seminar on Propellants,Explosives and Pyrotechnics)

会议地点: 西安

会议语种:英文

页码: 120-126

在线出版日期: 2007-10-23（万方平台首次上网日期，不代表论文的发表时间）