Design of Reactive Crystallization Fieldto Create Mono-dispersed and Nanosized Crystals
Control of size distribution through precipitation of strontium sulphate and calcium carbonate were performed in a solution containing polyethylenimine (PEI) and water-in-oil (w/o) -microemulsion. The important roles of PEI are the effect of chelation and protective colloid. Nucleation is considered to be controlled by the formation and the decomposition of polymer-cation complex, and crystal growth is considered to be restrained in the polymer-gel network. On the other hand, each microemulsion acts as like a microreactor, therefore, precipitates which have desired crystal size are considered to be possible to obtain nanosized crystals by controlling the size of microemulsion droplet.
Reactive crystallization Mono-dispersed nanocrystals Polyethylenimine Microemulsion
Takashi Mikami Shota Iked Izumi Hirasawa
Department of Applied Chemistry, Waseda University, 3-4-1 Ohkubo, Shinjyuku-ku, Tokyo 169-8555, Japan
国际会议
第四届中日化工学术研讨会(The 4th Joint China/Japan Chemical Engineering Symposium)(CJCES)
成都
英文
2007-12-19（万方平台首次上网日期，不代表论文的发表时间）