Unusual framework stabilization of Cu(II) and Cu(I) ions in a novel copper-substituted aluminophosphate with AEN topology prepared by one pot synthesis

摘要：

A novel copper-substituted aluminophosphate (CuIST-2) has been synthesized using methylamine as a templating agent. X-Ray diffraction studies provide evidence for an AEN topology similar to the parent Cu-free IST-2. An increase of the cell parameters suggested an isomorphous substitution of framework aluminium by copper. Combined cyclic voltammetry, H2-TPR, FTIR and cw EPR provide independent proof for an unusual framework position of Cu(II) ions in the as-synthesized phase and the further stabilization of both framework Cu(II) and Cu(I) in the air-calcined material.

作者: Z. Gabelica A. Fernandes M. F. Ribeiro J. P. Lourenco S. Valange A. Louati D. M. Murphy

作者单位: GSEC, ENSCMu, UHA, 3, rue Werner, F-68093 Mulhouse Cedex, France IBB, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisboa, Portugal Universidade do Algarve, Fac. Sci. Technol., DQB, P-8005-139 Faro, Portugal LACCO, UMR CNRS 6503, ESIP, Av. Rect. Pineau, F-86022 Poitiers Cedex, France LEA, ENSCMu, UHA, 3, rue A. Werner, F-68093 Mulhouse Cedex, France School of Chemistry, Main Building, Cardiff University, Cardiff CF10 3AT, UK

会议类型: 国际会议

会议名称: 第15届国际分子筛大会

会议地点: 北京

会议语种:英文

在线出版日期: 2007-08-12（万方平台首次上网日期，不代表论文的发表时间）