Structure orienting role of germanium in zeolite synthesis

摘要：

This paper deals with the synthesis results obtained from pure silica and (Si, Ge) systems in presence of hexamethonium cations, Kryptofix2,2,2 and 5-azoniaspiro4,5decane derivative cations as organic structure directing agents (OSDA) in hydroxide or fluoride media. The obtained new materials Mu-31, IM-9, IM-10 (UOZ), IM-11(LTA), IM-12 (UTL) all contain D4MR units, confirming the orienting effect of the germanium and/or the fluoride anions towards this small cage. Surprisingly, the extra-large pore IM-12 zeolite could not be obtained in the fluoride medium.

作者: J.-L. Paillaud Y. Lorgouilloux B. Harbuzaru P. Caullet J. Patarin N. Bats

作者单位: Laboratoire de Materiaux a Porosite Controlee, UMR CNRS 7016, ENSCMu, UHA, 3 rue Alfred Werner, 6809 Institut Francais du Petrole, CEDI Rene Navarre, BP3, 69590 Vernaison, France

会议类型: 国际会议

会议名称: 第15届国际分子筛大会

会议地点: 北京

会议语种:英文

在线出版日期: 2007-08-12（万方平台首次上网日期，不代表论文的发表时间）