Hydrothermal synthesis of boron-free Ti-MWW with dual structure-directing agents
Ti-MWW has been hydrothermally synthesized for the first time in the absence of crystallization-supporting agent of boron acid by means of cooperative templating effects of N,N,N-trimethyl-1-adamantammonium hydroxide (1-TMAda+OH-) and hexamethyleneimine (HMI). The use of potassium cations as a mineralization agent was also necessary for the crystallization. Boron-free Ti-MWW catalysts thus prepared showed a superior activity to boron-containing one in the liquid-phase epoxidation of alkenes with H2O2.
Na Liu Yueming Liu Wei Xie Lingling Wang Mingyuan He Peng Wu
Shanghai Key Lab of Green Chemistry and Chemical Processes, Department of Chemistry,East China Normal University, North Zhongshan Rd. 3663, Shanghai 200062
国际会议
北京
英文
2007-08-12（万方平台首次上网日期，不代表论文的发表时间）