Design of three-dimensional open-framework structures from inorganic clusters
A series of open-framework germanates and silicogermanates were synthesized (denoted as SU-n) hydro-/solvo-thermally. Their structures were built from a single or two types of inorganic clusters containing a number of well-defined Ge-O coordination polyhedra. Different arrangements and combinations of these clusters resulted in different openframework structures including some germanate/silicogermanates with extra-large pores (16- 24 rings). Herein we present our recently discovered crystalline structures of SU-3, SU-8, SU- 12, SU-44, SU-M and SU-MB. SU-M and SU-MB contain 30-ring channels and pores extending to the mesoporous range (> 20(A)).
Kirsten E. Christensen Lei Shi Liqiu Tang Tony Conradsson Mike S. Dadachov Xiaodong Zou
Structural Chemistry, Stockholm University, SE-106 91 Stockholm, Sweden Corpuscular Inc., 52 Papania Drive, Mahopac, NY 10541, USA
国际会议
北京
英文
2007-08-12（万方平台首次上网日期，不代表论文的发表时间）