A multidisciplary approach to understanding sorption induced breathing in the metal organic framework MIL53(Cr)

摘要：

A combination of methods (microcalorimetry, FTIR, Synchrotron XRD and molecular modelling) have been used to understand the sorption induced breathing with in the chromium metal organic framework MIL53. Strongly polar probes such as CO2 and H2O induce such breathing whereas non-polar molecules such as CH4 do not. In this system the breathing is strongly related to specific interactions between surface hydroxyls and the probe gas/vapour.

作者: S. Bourrelly C. Serre A. Vimont N. A. Ramsahye G. Maurin M. Daturi Y.Filinchuk G. Férey P. L. Llewellyn

作者单位: MADIREL (UMR CNRS 6121), Université de Provence. 13397. Marseille Cedex 20, France Institut Lavoisier (UMR CNRS 8180). Université de Versailles St-Quentin-en-Yvelines. 45, Avenue des Laboratoire Catalyse et Spectrochimie (UMR CNRS 6506), ENSICAEN-Batiment C, 6,Boulevard Maréchal Jui Laboratoire Physique de la Matière Condensée (UMR CNRS 5617), Université de Montpellier II. 34095. M SNBL at ESRF, BP-220, 38043, Grenoble, France

会议类型: 国际会议

会议名称: 第15届国际分子筛大会

会议地点: 北京

会议语种:英文

在线出版日期: 2007-08-12（万方平台首次上网日期，不代表论文的发表时间）