Towards predicting catalytic performances of zeolites

摘要：

The intrinsic activation energies of alkane activation reactions that involve the protonation of the reactant in the rate-limiting step are independent of zeolite structure and of Si/Al ratio. Their observed rates, however, increase with decreasing pore-sizes. Reactions that involve the formation and desorption of alkoxide species in their rate-limiting step strongly depend on the zeolite structure and on the interaction of the adsorbed molecule with the local environment of the acid site. There is a strong dependence on the Si/Al ratio.

作者: J. A. van Bokhoven B. Xu

作者单位: Department of Chemical and Bioengineering, ETH Zurich, HCI E115, Wolfgang-Pauli-Str.10, 8093 Zurich, Switzerland

会议类型: 国际会议

会议名称: 第15届国际分子筛大会

会议地点: 北京

会议语种:英文

在线出版日期: 2007-08-12（万方平台首次上网日期，不代表论文的发表时间）