Ethylene oligomerization over Ni-containing mesostructured catalysts with MCM-41, MCM-48 and SBA-15 topologies

摘要：

Nickel ion exchanged MCM-41, MCM-48 and SBA-15 mesostructured materials with a controlled concentration of nickel and acidic sites were prepared, characterized, and successfully used as catalysts in the ethylene oligomerization performed in slurry batch mode (T = 150℃, p = 3.5 MPa). Larger pores or a 3D pore system, as well as an equilibrated balance between acid and nickel ion sites were very favorable for the oligomerization process.

作者: M. Lallemand A. Finiels F. Fajula V. Hulea

作者单位: Institut Charles Gerhardt, UMR 5253, CNRS-UM2-ENSCM- UM1, Laboratoire de Matériaux Avancés pour la Catalyse et la Santé, 8 rue de l’Ecole Normale, 34 296 Montpellier Cedex 5,France

会议类型: 国际会议

会议名称: 第15届国际分子筛大会

会议地点: 北京

会议语种:英文

在线出版日期: 2007-08-12（万方平台首次上网日期，不代表论文的发表时间）