Shape selective adsorption of linear and branched alkanes in the Cu3(BTC)2 metal-organic framework

摘要：

Low coverage adsorption properties of C2-C7 linear and C5-C7 iso-alkanes are measured. Shape selective properties of the Cu3(BTC)2 MOF are determined using the pulse chromatographic technique. Preferential adsorption of linear over methylbranched alkanes is observed. Linear alkanes fit better in the pores resulting in stronger interaction with the framework atoms, and thus longer retention.

作者: Vincent Finsy Selm De Bruyne Luc Alaerts Dirk De Vos Pierre A. Jacobs Gino V.Baron Joeri F. M. Denayer

作者单位: Department of Chemical Engineering, Vrije Universiteit Brussel, Pleinlaan 2, B-1050 Brussel, Belgium Center for Surface Chemistry and Catalysis, Katholieke Universiteit Leuven, Kasteelpark Arenberg 23,

会议类型: 国际会议

会议名称: 第15届国际分子筛大会

会议地点: 北京

会议语种:英文

在线出版日期: 2007-08-12（万方平台首次上网日期，不代表论文的发表时间）