A New Way of Step-mass-thermal Transferring to Control Phase Separation for Polyacrylonitrile (PAN)/DMSO/Water System
The step-mass-thermal transferring for PAN/DMSO/Water system was proposed to control the kinetic of phase separation and droplet ripening. In this way, the morphology of fiber could be regulated by employing several consecutive coagulation baths with different concentrations and temperatures based on modelling. Phase diagram of ternary system about PAN/DMSO/water was calculated according to Flory-Huggins theory. The mass and thermal transferring was calculated using Ficks second law and Fourier heat equation respectively.
Step-mass-thermal transferring Phase diagram
JIANG Bingxin WU Chengxun YU Xianfu GUO Lizhong SHI Yongchun
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Stare Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Air Force College, Xuzhou, Jiangsu 221000, P. R. China
国际会议
上海
英文
25-27
2007-10-15(万方平台首次上网日期,不代表论文的发表时间)